Synthesis of a new disaccharide: O-β-d-glucopyranosyl-(1→3)-d-fructose (laminarabiulose)
✍ Scribed by Alicia Couto; Rosa M. de Lederkremer
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 446 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0008-6215
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The disaccharides 4-O-/3-D-glucopyranosyl-D-glucosamine (GIc-GIcN) and 4-O-fl-D-glucopyranosyl-2-deoxy-o-glucose (Glc-2-deoxy-Glc) were synthesized from equimolar amounts of D-glucosamine and a-D-glucose-l-phosphate (G-l-P), and 2-deoxy-o-glucose and at-D-glucose-Iphosphate (G-l-P) respectively, in
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## Abstract 13‐__O__‐β‐D‐Glucopyranosylgibberellin A~5~ β‐D‐glucopyranosyl ester (2a) was synthesized by base‐catalyzed (triethylamine) reaction of gibberellin A~5~ 13‐__O__‐β‐D‐glucopyranoside (4a) with α‐acetobromoglucose followed by mild sodium methanolate deacetylation. Structures of the gibber