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Synthesis of a New Class of Highly Functionalized Phosphorus Ylides Containing Heterocyclic Compounds

✍ Scribed by Ahmad Shaabani; Sajjad Keshipour; Morteza Aghaei; M. Hassan Khodabandeh; Mansour Zahedi

Book ID
115554499
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
742 KB
Volume
30
Category
Article
ISSN
0256-7660

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AbstractÐProtonation of the reactive 1:1 intermediates produced in the reaction between triphenylphosphine and dialkyl acetylenedicarboxylates by 3-chlorotetrahydrofuran-2,4-dione leads to vinylphosphonium salts, which undergo Michael addition with the conjugate base of the CH-acid to produce highly