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Synthesis of a modified fragment 13–19 of the sequence of ACTH using silyl protection

✍ Scribed by V. N. Karel'skii; E. P. Krysin; A. K. Rabinovich; A. A. Antonov; M. B. Smirnov

Book ID
112373620
Publisher
Springer
Year
1980
Tongue
English
Weight
437 KB
Volume
16
Category
Article
ISSN
0009-3130

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✍ Mukund K Gurjar; Siddhartha Ray Chaudhuri 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 261 KB

A stereo-controlled radical C C bond formation involving a 5-chloro-5-deoxy-L-idofurano-6,3-lactone derivative and allyltri-n-butyltin/AIBN is described. Further elaboration led to the synthesis of the C13 C19 segment of sanglifehrin A.