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Synthesis of a model of chloropeptins I, II western subunit by the intramolecular SNAr based methodology

✍ Scribed by Georges Roussi; Eduardo González Zamora; Annie-Claude Carbonnelle; René Beugelmans

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 202 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00938-6

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✦ Synopsis

Formation of a biaryl ether bond between the termini of a tetrapeptide containing a highly racemization prone amino acid by the intramolecular SNAr reaction afforded two diastereomeric 16membered macrocycles along with their respective atropoisomers. The (R,S,R) and its atropoisomer constituted a model of chloropeptins L H western part.

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