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Synthesis of a hypothetical intermediate in the biosynthesis of the 13-methylbenzophenanthridine alkaloids corynoline and 14-epicorynoline and the B-secoprotoberberine alkaloid corydalic acid methyl ester

✍ Scribed by Mark Cushman; Wai Cheong Wong


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
208 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis


A novel carbinolammonium chloride has been synthesized as a possible intermediate in the biosynthetic conversion of the 13-methylprotoberberine alkaloid (+)-tetrahydrocorysamine to the benzophenanthridine alkaloids (+)-corynoline, (+)-14-epicorynoline, and the Bsecoprotoberberine alkaloid (+)-corydalic acid methyl ester.