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Synthesis of a Highly Unsaturated, Stable Hydroxy Peroxide: A Yellow [lrarr2] Blue Color-Changing Carotenoid Oxidation Product with Leuco Dye Properties

✍ Scribed by He Li; Edouard Rebmann; Christer L. Øpstad; Rudolf Schmid; Hans-Richard Sliwka; Vassilia Partali


Book ID
102176383
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
406 KB
Volume
2010
Category
Article
ISSN
1434-193X

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✦ Synopsis


Abstract

A stable, highly unsaturated hydroxy peroxide was synthesized by reacting a common food color carotenoid with FeCl~3~ in air. The obtained pale‐yellow carotenoid hydroxy peroxide is easily converted into a blue, cationic polyene – then changes back to the yellow compound, showing the same characteristically dichromic properties like polycyclic, aromatic leuco dyes.