✦ LIBER ✦
Synthesis of a halo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3′-dimethyl-biphenyl linker using tris(halo-methylphenylene)triazines as building blocks
✍ Scribed by Ioannis D. Kostas; Fotini J. Andreadaki; Elaine A. Medlycott; Garry S. Hanan; Eric Monflier
- Book ID
- 104096266
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- French
- Weight
- 211 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A tris(bromo-methylphenylene)triazine and its corresponding phosphine oxide derivative have been synthesized; the latter compound was found to be a potent ligand for the hydroformylation reaction. Suzuki coupling of the mono-pinacolboronate derivative of the former compound with a tris(iodo-methylphenylene)triazine was possible at two of the three iodine atoms, yielding a bromo-and iodo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3 0 -dimethyl-biphenyl linker.