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Synthesis of a cumyl analogue in nitrothiazole series and SRN1 reaction at tertiary carbon

✍ Scribed by Armand Gellis; Patrice Vanelle; José Maldonado; Michel P. Crozet

Book ID: 104256614
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 124 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00243-8

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✦ Synopsis

A new alkylating agent, 2-(1-methyl-l-nitroethyl)-5-nitrothiazole, bearing a tertiary nitro nucleofuge, reacts with 2-nitropropane anion by SRN1 mechanism leading to the C-alkylation product.

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