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Synthesis of a Coumarin Compound from Phenanthrene by a TiO2-Photocatalyzed Reaction.

โœ Scribed by Suguru Higashida; Aiko Harada; Rikako Kawakatsu; Noriko Fujiwara; Michio Matsumura


Publisher
John Wiley and Sons
Year
2006
Weight
11 KB
Volume
37
Category
Article
ISSN
0931-7597

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Generation and diels-alder reactions of
โœ Gordon W. Gribble; Edward J. Holubowitch; Michael C. Venuti ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

In 1959 Cava reported' that a,a'-dibromo-c-quinodimethane (z), generated by treatment of a,a,a',a'-tetrabromo-o-xylene (1) with NaI in warm DMF, --could be trapped by dienophiles to give 2,3-disubstituted naphthalenes. Cava's scheme is shown below with &phenylmaleimide as the trapping agent.