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Synthesis of a chiral micelle-like dendrimer with phenylene dendrons and a 1,1′-binaphthyl core

✍ Scribed by Liu-Zhu Gong; Lin Pu

Book ID: 104231618
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 251 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01569-6

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✦ Synopsis

A novel chiral micelle-like dendrimer has been synthesized. This dendrimer contains a chiral binaphthyl core, meta-phenylene dendrons, and hydrophilic polyhydroxyl periphery groups. It is soluble in highly polar solvents such H 2 O/THF, MeOH/THF, EtOH/THF and DMSO, but insoluble in EtOAc, CH 2 Cl 2 and CHCl 3 . The study by UV-vis absorption spectroscopy reveals that the dendrimer may have a tighter conformation in a less polar solvent than in a more polar solvent. This dendrimer shows strong fluorescence in solution.

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