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Synthesis of a chiral dioxo-cyclam derived from L-phenylalanine and its application to olefin oxidation chemistry

✍ Scribed by Thomas R. Wagler; Cynthia J. Burrows

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 282 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)80687-5

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✦ Synopsis

An optically active dioxo-&am macrocycle bearing two benzyl side chains derived from phenylalanine has been synthesized; its Ni(II) complex catalyzes the oxidation of olejins using hypochlorite under phase transfer conditions.

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