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Synthesis of a cellulose xanthate supported palladium(0) complex and its catalytic behavior in the Heck reaction

โœ Scribed by Ying Xu; Man Xue; Jinjin Li; Liujie Zhang; Yuanchen Cui

Book ID
106513135
Publisher
Springer-Verlag
Year
2010
Tongue
English
Weight
878 KB
Volume
100
Category
Article
ISSN
1878-5190

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A silica-supported poly-โฅ-diphenylarsinopropylsiloxane palladium complex has been prepared from โฅ-chloropropyltriethoxysilane via immobilization on fumed silica, followed by reacting with potassium diphenylarsenide in THF and then the reaction with palladium chloride. It is an efficient catalyst for