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Synthesis of [8,9-3H2]-(7S)-methoprene, a juvenile hormone analog, by selective reduction of a protected trienoate

✍ Scribed by Marcus F. Boehm; Glenn D. Prestwich

Publisher: John Wiley and Sons
Year: 1988
Tongue: French
Weight: 276 KB
Volume: 25
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2580250610

No coin nor oath required. For personal study only.

✦ Synopsis

High specific activity 3H-(7S)-methoprene is prepared in seven steps from (3S)-citronellol by the use of iron tricarbonyl to protect the dienoate moiety of isopropyl (2E94E)-3,7,1 l-trimethyl-2,4,8-dodecatrienoate during heterogeneous mtiation of remote olefinic bond.

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