𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of (+)-8-Deoxyvernolepin and Its 11,13-Dihydroderivative. A Novel Reaction Initiated by Sulfene Elimination Leads to the 2-Oxa- cis -decalin Skeleton

✍ Scribed by Barrero, Alejandro F.; Oltra, J. Enrique; Álvarez, Míriam; Rosales, Antonio


Book ID
120554895
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
145 KB
Volume
67
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


A new strategy for the synthesis of (+)-
✍ Alejandro F Barrero; J.Enrique Oltra; Mı́riam Álvarez 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 102 KB

A new strategy for the synthesis of (+)-vernolepin (1), (+)-vernodalin (2), and (+)-8-deoxyvernolepin (3), from the accessible germacrolides (+)-salonitenolide ( 4) and (+)-costunolide (5), has been developed. The key steps in the synthesis are a Cope rearrangement from the germacradiene to the elem