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Synthesis of 7a-Aryl-5-tbutyl-3-methyleneoctahydrobenzofuran (IV) Possessing Partial Skeletons of Some Santonin Analogue and Furanolignans by Intramolecular Radical Cyclization Reaction.

✍ Scribed by Marappagounder Periasamy; Alagusundaram Ponnuswamy

Publisher: John Wiley and Sons
Year: 2007
Weight: 19 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200747109

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✦ Synopsis

Abstract

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Synthesis of 7a-aryl-5-t-butyl-3-methyle

Synthesis of 7a-aryl-5-t-butyl-3-methyleneoctahydrobenzofuran possessing partial skelotons of some santonin analogue and furanolignans by intramolecular radical cyclisation reaction

✍ Marappagounder Periasamy; Alagusundaram Ponnuswamy 📂 Article 📅 2007 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 329 KB

## Abstract magnified image Bicyclic octahydrobenzofuran derivatives (**1c‐6c**) possessing the partial skeletons of santonin (**7**), 11,13‐dehydroisohyposantonin (**8**), dihydrosesamin (**9**) and lariciresinol (**10**) have been synthesised by intramolecular radical cyclisation in good yield _