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Synthesis of 7-Azabicyclo[2.2.1]heptane and 2-Oxa-4-azabicyclo[3.3.1]non-3-ene Derivatives by Base-Promoted Heterocyclization of Alkyl N -( cis ( trans )-3, trans ( cis )-4-Dibromocyclohex-1-yl)carbamates and N -( cis ( trans )-3, trans ( cis )-4-Dibromocyclohex-1-yl)-2,2,2-trifluoroacetamides

✍ Scribed by Gómez-Sánchez, Elena; Soriano, Elena; Marco-Contelles, José


Book ID
121495035
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
414 KB
Volume
72
Category
Article
ISSN
0022-3263

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## Abstract magnified image A short and efficient protocol for the stereoselective synthesis of racemic __trans‐__ and __cis‐__3,4‐dihydro‐3,4,8‐trihydroxynaphthalen‐1(2__H__)‐one (**1** and **2**, resp.), is described, comprising nine and eight steps starting from commercial juglone (=5‐hydroxyna