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Synthesis of 6,6-bisbenzannulated spiroketals related to the rubromycins using a double intramolecular hetero-Michael addition (DIHMA)

✍ Scribed by Peter J. Choi; Dominea C.K. Rathwell; Margaret A. Brimble

Book ID
108285409
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
487 KB
Volume
50
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Synthesis of 6,6-Bi
ChemInform Abstract: Synthesis of 6,6-Bisbenzannulated Spiroketals Related to the Rubromycins Using a Double Intramolecular Hetero-Michael Addition (DIHMA).
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Application of a novel double intramolecular hetero-Michael addition (DIHMA) strategy to spiroketal synthesis was illustrated by a concise synthesis of (Β±)-(4S\*,6S\*)-4-hydroxy-1,7-dioxaspiro[5.5]undecane, a Dacus oleae olive fly pheromone.