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Synthesis of 6-epicastanospermine and 1,6-diepicastanospermine from L-gulonolactone and synthesis of L-6-epicastanospermine and L-1,6-diepicastanospermine from D-gulonolactone

โœ Scribed by George W.J. Fleet; Nigel G. Ramsden; Russell J. Molyneux; Gary S. Jacob


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
317 KB
Volume
29
Category
Article
ISSN
0040-4039

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Chemoenzymatic synthesis of 6-deoxy-D-fr
โœ Laurence Hecquet; Jean Bolte; Colette Demuynck ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 514 KB

A chemoenzymatic route to 6-deoxy (D-fructose 5b and L-sochose 5a) is described.This method is based on conversion of racemic 2.3-dihydroxybutyraldehyde to 5a and Sb catalyzed by spinach leaves Transketolase. Only the (R,R) and (R,S) isomers of 2,3-dihydroxybutymkiehyde react, yielding 6-deoxy-D-fmc