A new and efficient route to (-)-(1R,2R,4R,6S)-l,6-epoxy-4-benzyloxycyclohexan-2-ol is described starting from (-)-quinic acid. The pivotal step involves a La3+-induced reversal of the diastet~eoselectivity for the borchydride reduction of an imm'medi~ cyclnhexan-4-one. (IR,2R,4R,6R)-6-Propyloxycycl
β¦ LIBER β¦
Synthesis of 6-amino-3,5-deoxyinositol 1-phosphates via (1R,2R,4R,6S)-1,6-Epoxy-2,4-bis-benzyloxycyclohexane aminolysis in aqueous ytterbium triflate solution
β Scribed by Martin Beaton; David Gani
- Book ID
- 104260133
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 262 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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