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Synthesis of 5H,7H-dibenzo[b,g][1,5]selenoxocine from a selenonium salt of 5H,7H-dibenzo[b,g][1,5]diselenocine and first X-ray evidence for the transannular oxygen-selenium interaction

✍ Scribed by Hisashi Fujihara; Tsukasa Nakahodo; Naomichi Furukawa

Book ID
103403969
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
224 KB
Volume
36
Category
Article
ISSN
0040-4039

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Conformational features and chemical beh
Conformational features and chemical behavior of 5H, 7H-dibenzo[B,g][1,5] dithiocin oxides: 1,5-Oxygen shift via a dithiodication intermediate
✍ Katsuo Ohkata; Keiji Okada; Kin-Ya Akiba πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 769 KB

## Abstract Some 5H,7H‐dibenzo[b,g][1,5]dithiocin oxides (4–8) and their related compounds 9–13 were prepared and the assignment of the most favorable conformation was carried out on the basis of the characteristic ^1^H NMR spectral data. Only a single conformer (BC: boatchair form) exists for 4,5,