𝔖 Bobbio Scriptorium
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Synthesis of 5′-Amido Analogs of Adenosine (3′-5′)-Cyclophosphates

✍ Scribed by Dr. Akira Murayama; Dr. Bernd Jastorff; Dr. Hans Hettler

Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
225 KB
Volume
9
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis

pectively (e.g. for (2a) in CC14: v, , (CSj) = 1146vw, vs(CS2) = 61 9 cm-1 vs). Spectroscopic and X-ray data indicate pseudooctahedral environment of the metal in (/a)--( 2f) with (pseudo)-Czv symmetry. The IH-NMR spectra indicate in particular that an isomeric mixture containing (Ze) and a tolyldithiocarboxylato derivative is only formed on reaction of C6HsCH2Re(C0)5 with CS2. The dithiocarboxylato complexes described above are reactive. For instance, (2b) loses CO on reaction with P(CGHS)~ at 80 "C in benzene to give the stable orange compound cis-

C G H ~C ( S ) S R ~( C O ) ~P ( C ~H ~) ~

(dec. pt. 190 "C).

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