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Synthesis of 4,6-dihydroxyisophthalaldehyde and the 5-methyl and 5-methoxy-derivatives

โœ Scribed by Worden, Leonard R.; Kaufman, Kurt D.; Smith, Patricia J.; Widiger, Gary N.


Book ID
118209623
Publisher
The Royal Society of Chemistry
Year
1970
Tongue
English
Weight
523 KB
Volume
2
Category
Article
ISSN
0022-4952

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Synthesis of (5R)- and (5S)-5-Methyl-5,
โœ Vinko ล kariฤ‡; Jasenka Matuliฤ‡-Adamiฤ‡ ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 453 KB

## Abstract The hydrogenation of 2โ€ฒ, 3โ€ฒโ€__O__โ€isopropylideneโ€5โ€methyluridine **(1)** in water over 5% Rh/Al~2~O~3~ gave (5 __R__)โ€ and (5 __S__)โ€5โ€methylโ€5, 6โ€dihydrouridine **(2)**, separated as 5โ€ฒโ€__O__โ€(__p__โ€tolylsulfonyl)โ€ **(3)** and 5โ€ฒโ€__O__โ€benzoylโ€ **(5)** derivatives by preparative TLC. o