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Synthesis of 4-stannylated tamoxifen analogues; useful precursors to radiolabelled idoxifene and aziridinyl 4-iodotamoxifen

✍ Scribed by Raymond McCague; Gerard A. Potter


Publisher
John Wiley and Sons
Year
1994
Tongue
French
Weight
321 KB
Volume
34
Category
Article
ISSN
0022-2135

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✦ Synopsis


Abstract

The 4‐stannylated tamoxifen analogues (E)‐1‐[4‐[2‐(N‐pyrrolidino)ethoxy]phenyl]‐1‐[4‐(tributylstannyl)phenyl]‐2‐phenyl‐1‐butene and (E)1‐[4‐[2‐(aziridin‐1‐yl)ethoxy]phenyI]‐1‐[4‐(tributylstannyl)phenyl]‐2‐phenyl‐1‐butene have been synthesised as precursors to radiolabelled idoxifene, an important new drug for the treatment of breast cancer, and to aziridinyl 4‐iodotamoxifen, a potentially useful biological research tool for studying the action of tamoxifen, respectively.