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Synthesis of 4-keto pimelates by palladium-catalyzed carbonylativesymmetrical coupling of siloxycyclopropanes

✍ Scribed by Satoshi Aoki; Eiichi Nakamura; Isao Kuwajima


Book ID
108381647
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
125 KB
Volume
29
Category
Article
ISSN
0040-4039

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Palladium-catalyzed mtion of a silcncy~cloptvpane with an a@ tri@te under carbon monari& pr~ssum (10-20 atm) in HMPA and that with carbon monoxide in chloroform provides new synthetic routes to 1,4-dicarbonyl compounds and I-keto pimelates, respectively. The reaction of a sikqycycloprvpane with a vi