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Synthesis of 4-Hydroxyquinolines. II. Preparation Through 3-Cyano and 3-Carbanilido Derivatives 1

โœ Scribed by Price, Charles C.; Leonard, Nelson J.; Herbrandson, Harry F.


Book ID
127237394
Publisher
American Chemical Society
Year
1946
Tongue
English
Weight
261 KB
Volume
68
Category
Article
ISSN
0002-7863

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A facile synthesis of 2-cyano-4H-3,1- be
โœ Hyunil Lee; Kyongtae Kim ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 812 KB

## Treatment of the hydrochloride salts of 4-chloro-5-(2halomethylaryl-imino)-5H-l,2,3-dithiazoles (2) with sodium cyanoborohydride in THF at room temperature gave 2-cyan0-4H-3,l -benzothiazines ( I ) in good to moderate yields. 2-Cyano-4H-3,l -benzoxazines (4) were obtained in good to moderate yiel