Synthesis of 4-C-methyl and 4-C-allyl derivatives of sucrose
โ Scribed by Albert K.B. Chiu; Leslie Hough; Anthony C. Richardson; Imad A. Toufeili; Stanley Z. Dziedzic
- Book ID
- 107725650
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 419 KB
- Volume
- 162
- Category
- Article
- ISSN
- 0008-6215
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๐ SIMILAR VOLUMES
Benzyl 2,3,6-tri-O-benzyl-4-deoxy-4-C-methylenea\_Dranoside (3) was transformed with 3-chloroperoxybenzoic acid into the epoxides 4 and 5. Reductive opening of the epoxide moiety in 4 furnished benzyl 2,3,6-tri-O-benzyl-4-C-methyl-a-o-glucopyranoside (6); subsequent hydrogenolytic Odebenzylation, pe
The 2,1'-0-isopropylidene derivative (1) of 3-O-acetyl-4,6-O-isopropylidenecu-~glucopyranosyl 6-O-acetyl-3,4-anhydro-fl-D-lyxo-hexulofuranoside and 2,3,4tri-O-acetyl-6-O-trityl-cY-D-glucopyranosyl 3,4-anhydro-1,6-di-0-trityl-@-D-lyxohexulofuranoside have been synthesised and 1 has been converted int