𝔖 Bobbio Scriptorium
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Synthesis of 4-aminoquinuclidine and its derivatives

✍ Scribed by E. E. Mikhlina; N. A. Komarova; M. V. Rubtsov


Book ID
112441285
Publisher
Springer US
Year
1972
Tongue
English
Weight
189 KB
Volume
5
Category
Article
ISSN
0009-3122

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Synthesis of 4-aminoguaiazulene and its
✍ Alexandros Kiriazis; Ingo B. AumΓΌller; Jari Yli-Kauhaluoma πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 French βš– 292 KB

A method for nitrogen insertion into guaiazulene hydrocarbons is developed. A one-pot reaction of 7-isopropyl-1-methylazulene-4-carboxylic acid, diphenylphosphoryl azide, and an alcohol (MeOH, t BuOH or BnOH) affords the corresponding carbamates. Deprotection of benzyl (7-isopropyl-1-methylazulen-4y