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Synthesis of 4-Alkyl-4-alkoxybutenolides Having Unsaturated Side Chains via Chromium Carbene Complex Photochemistry: (+)-Cerulenin

โœ Scribed by Kedar, Tracey E.; Miller, Michael W.; Hegedus, Louis S.


Book ID
115520375
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
299 KB
Volume
61
Category
Article
ISSN
0022-3263

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Synthesis of 4-Alkyl-4-alkoxybutenolides Having Unsaturated Side Chains via Chromium Carbene Complex Photochemistry: (+)-Cerulenin. -The photochemical reaction of Cr alkoxycarbene complexes, e.g. (I), with optically active ene carbamates, e.g. (S)-(II), followed by Baeyer-Villinger oxidation of the