✦ LIBER ✦

Synthesis of 4-acylindoles via 2-(2-phenylsulfinylvinyl)pyrrole.

✍ Scribed by Joseph M. Muchowski; Markus E. Scheller

Book ID: 104227740
Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 207 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96324-x

No coin nor oath required. For personal study only.

✦ Synopsis

I-Acylindoles are readily obtained by the [4x + 2x1 cycloaddition of l-triisopropylsilyl-trans-2-(2-phenylsulfinylvinyl)pyrrole with electron deficient acetylenes followed by N-desilylation of the cycloadducts with fluoride ion.

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