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Synthesis of 4-Acetylbenzoxazolin-2(3 H )-one Reported from Zea m ays

✍ Scribed by Kluge, Michael; Sicker, Dieter

Book ID
120386837
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
27 KB
Volume
61
Category
Article
ISSN
0163-3864

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Biomimetic synthesis of 4-acetylbenzoxaz
Biomimetic synthesis of 4-acetylbenzoxazolin-2(3H)-one isolated from Zea mays
✍ Carlos A. Escobar; Michael Kluge; Dieter Sicker πŸ“‚ Article πŸ“… 1997 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 589 KB

## Abstract 4‐Acetylbenzoxazolin‐2(3__H__)‐one has been prepared biomimetically during attempts to synthesize the hemiacetalic hydroxamic acid 5‐acetyl‐2,4‐dihydroxy‐2__H__‐1,4‐benzoxazin‐3(4__H__)‐one by the immediate degradation of this unstable compound generated as an intermediate. Thus, 4‐acet