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Synthesis of 4′-(4‴-benzo-15-crown-5)-methyloxy-2,2′:6′,2″-terpyridine (L) and the crystal structure of its complexes with cobalt(II) and zinc(II): [ML2](ClO4)2· 3H2O

✍ Scribed by A. Yu. Tsivadze; V. E. Baulin; M. S. Grigor’ev; N. M. Logacheva; A. V. Shnipov


Book ID
110182107
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
230 KB
Volume
53
Category
Article
ISSN
0036-0236

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Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a