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Synthesis of [4-15NH2]- and [1,3-15N2]cytidine derivatives for use in NMR-monitored binding tests

✍ Scribed by Chien-Hua Niu

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 330 KB
Volume: 139
Category: Article
ISSN: 0003-2697
DOI: 10.1016/0003-2697(84)90025-3

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✦ Synopsis

The conversion of 15N-enriched urea to a [1,3-15N2]cytidine derivative is accomplished in nine steps with an overall yield of 67%. Synthesis of a [4-15NH2]cytidine derivative is achieved by thiolation of the corresponding uridine derivative with Lawesson's reagent and amination with 15N-enriched ammonia in a sealed glass vessel.

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