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Synthesis of (3R,25R)-3,25-dihydroxyhexacosyl α-D-glucopyranoside, the heterocyst glycolipid of the marine cyanobacteriumNodularia harveyana

✍ Scribed by Mori, Kenji ;Qian, Zhao-Hui

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 465 KB
Volume: 1994
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199419940108

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

(3__R__,25__R__)‐3,25‐Dihydroxyhexacosyl α‐D‐glucopyranoside (1a), the heterocyst glycolipid of Nodularia harveyana, was synthesized by starting from D‐glucose, (S)‐malic acid (4), 1‐octadecyne (5) and ethyl (R)‐3‐hydroxybutanoate (6). magnified image

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