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Synthesis of 3,5-diaryl-4-chlorophthalates by [4+2] cycloaddition of 1-ethoxy-2-chloro-1,3-bis(trimethylsilyloxy)-1,3-diene with dimethyl acetylenedicarboxylate and subsequent site-selective Suzuki–Miyaura reactions

✍ Scribed by Obaid-Ur-Rahman Abid; Muhammad Farooq Ibad; Muhammad Nawaz; Muhammad Adeel; Nasim Hasan Rama; Alexander Villinger; Peter Langer


Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
319 KB
Volume
51
Category
Article
ISSN
0040-4039

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Regioselective Synthesis of 4-(Arylsulfa
✍ Muhammad Imran; Inam Iqbal; Christine Fischer; Peter Langer 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 142 KB

## Abstract The [4+2] cycloaddition of 3‐(arylsulfanyl)‐1‐(trimethylsilyloxy)buta‐1,3‐dienes with dimethyl penta‐2,3‐dienedioate provides a convenient and regioselective approach to a variety of 4‐(arylsulfanyl)‐2‐hydroxyhomophthalates.