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Synthesis of 3,3-Disubstituted Isoindolin-1-ones via Iodoamination of α-Substituted Secondary 2-Vinylbenzamides.

✍ Scribed by Kazuhiro Kobayashi; Masanori Hase; Kenichi Hashimoto; Seiki Fujita; Miyuki Tanmatsu; Osamu Morikawa; Hisatoshi Konishi

Publisher
John Wiley and Sons
Year
2006
Weight
21 KB
Volume
37
Category
Article
ISSN
0931-7597

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Hydriodic Acid-Mediated Cyclization of α
Hydriodic Acid-Mediated Cyclization of α-Substituted Secondary 2-Ethenylbenzamides: Synthesis of 2-Substituted 2,3-Dihydro-3,3-dimethyl-1H-isoindol-1-ones and 3,3-Disubstituted (E)-1-(Arylimino)-1,3-dihydroisobenzofurans
✍ Kazuhiro Kobayashi; Seiki Fujita; Daisuke Nakai; Shogo Fukumoto; Shuhei Fukamach 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 168 KB 👁 1 views

## Abstract A new and facile method for the preparation of 2‐substituted 2,3‐dihydro‐3,3‐dimethyl‐1__H__‐isoindol‐1‐ones **3** and 3,3‐disubstituted (__E__)‐1‐(arylimino)‐1,3‐dihydroisobenzofurans **6** has been developed. Thus, treatment of __N__‐alkyl(or aryl)‐2‐(1‐methylethen‐1‐yl)benzamides **2