SYNTHESIS OF 3-SELENA-7-AZABICYCLO[3.3.1]NONANES AND CERTAIN DERIVATIVES
β Scribed by Thompson, M. Daniel; Smith, Gary S.; Berlin, K. Darrell
- Book ID
- 121286298
- Publisher
- Taylor and Francis Group
- Year
- 1986
- Tongue
- English
- Weight
- 586 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0030-4948
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π SIMILAR VOLUMES
A series of selenanes and selenanones have been examined using "Se NMR analysis. Sharp resonances were found in all cases whether recorded at 47.7, 51.4 or 57.22MHz or in DCCI, or DMSO-&. Diphenyl diselenide was used as the external reference, but all resonances were subsequently referred to dimethy
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract The azabicyclic __endo__ compound 3 was synthesized by reaction of enamine 1 with 2βbenzoylβ1,3βdichloropropane (2). The thermodynamically more stable __exo__ isomer 4 was obtained by epimerization of 3 with sodium methoxide. The reduction of 3 and 4 was carried out with different reduc