Synthesis of 3-methyl-1,3,5-pentanetriol and its mono- and diesters
โ Scribed by Enzo Santaniello; Rosangela Casati; Lucio Ceriani; Patrizia Ferraboschi; Paride Grisenti
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 262 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0009-3084
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โฆ Synopsis
3-Methyl-l,3,5-pentanetriol has been prepared by an improved ozonolysis procedure and some of its diesters have been synthesized. Monooctanoate of the above triol was prepared by enzymatic hydrolysis of dioctanoate (54% fields of isolated product) using porcine pancreas lipase (PPL) as biocatalyst.
๐ SIMILAR VOLUMES
Shikimic acid (~-1) was first isolated from the oriental plant Illicium religiosum (in Japanese, shikimi) in 1885 by Eijkma&. After nearly 50 years, thanks to the pioneering works of Fischer and Dangschat4 during the 1930's, the complete structure and absolute stereochemistry of this acid were estab