Tetralone 1 Pentanoic acid, 3-carboxy 1 Furandione The synthesis of 3-carboxy-4-(trifluoromethyl)tetralone'~2~, a model compound which is important for the preparation of perfluoroalkyl-substituted tetracyclines, is an offshoot of an attempted synthesis of the hydroxytetralone 2. Some of the results
Synthesis of 3-carboxy-4-(trifluoromethyl)tetralone
✍ Scribed by Ukerun, Sylvester Ohwevwo
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 221 KB
- Volume
- 1988
- Category
- Article
- ISSN
- 0947-3440
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📜 SIMILAR VOLUMES
The crystal structure of the title compound, C~7~H~7~F~3~N^+^·C~8~H~3~Cl~2~O~4~ ^−^, is stabilized by five N—H...O, one O—H...O, two C—H...O and three C—H...__X__ (__X__ = F, Cl) hydrogen bonds. Intramolecular O—H...O and C—H...__X__ hydrogen bonds generate edge-fused [__S__(7)__R__ ~4~ ^4^(24)__S__
The Cu atom in the title compound, [Cu(C 7 H 5 O 6 S)-(C 10 H 8 N 2 )](C 7 H 5 O 6 S), is chelated by the two N-heterocycles and is covalently bonded to the sulfonate O atom of the sulfosalicylate ion in a trigonal±bipyramidal geometry. The uncoordinated sulfosalicylate anion interacts with adjacent