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Synthesis of 3-Azabicyclo[3.3.0]octane Framework and a Novel Tricyclicaminoether

✍ Scribed by Kaniskan, H. Ümit; Dogan, Özdemir

Book ID
121303048
Publisher
Taylor and Francis Group
Year
2003
Tongue
English
Weight
225 KB
Volume
33
Category
Article
ISSN
0039-7911

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✍ Emerson P Peçanha; Hugo Verli; Carlos R Rodrigues; Eliezer J Barreiro; Carlos A. 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 353 KB

In this paper we described the synthesis of the cis-2-azabicyclo[3.3.0]octane derivative (5b) employing highly diastereoselective mercury(II)-mediated intramolecular amino-cyclization, followed by reductive demercuration of ethyl erythro-1allyl-2-amino-1-cyclopentanecarboxylate (7b). Molecular dynam