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Synthesis of 3-aryl(hetaryl)-1,2,3-diazaphospholines

✍ Scribed by Aleksandra A. Chaikovskaya; Tamara N. Kudrya; Aleksandr I. Lakhtadir; Radomir V. Smaliy; Aleksandr M. Pinchuk; Andrei A. Tolmachev

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 67 KB
Volume: 16
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20074

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✦ Synopsis

Abstract

A reaction of cyclohexanone phenylhydrazone with (het)aryldihalogenophosphines has been studied. As shown, cyclohexanone phenylhydrazone reacts with phenyldibromophosphine and 5‐methyl‐2‐furyldibromophosphine to provide the corresponding 1,2,3‐diazaphospholines in high yields. The diazaphospholines thus obtained have been derivatized. © 2005 Wiley Periodicals, Inc. Heteroatom Chem 16:81–83, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20074

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