𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of 3-aryl-5-styryl-2-pyrazolines by the reaction of (E,E)-cinnamylideneacetophenones with hydrazines and their oxidation into pyrazoles

✍ Scribed by Albert LÉvai; TamÁs Patonay; Artur M. S. Silva; Diana C. G. A. Pinto; José A. S. Cavaleiro


Publisher
Journal of Heterocyclic Chemistry
Year
2002
Tongue
English
Weight
72 KB
Volume
39
Category
Article
ISSN
0022-152X

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

New 3‐aryl‐5‐styryl‐2‐pyrazolines have been synthesized by the reaction of (E,E)‐cinnamylideneace‐tophenones with hydrazines. These 2‐pyrazolines have also been converted into the corresponding pyrazoles by oxidation with chloranil. Structures of all new compounds have been elucidated by elemental analysis, mass spectrometry, ir and nmr spectroscopic measurements.


📜 SIMILAR VOLUMES


Synthesis of 1-substituted 5-aryl-3-styr
✍ Albert Lévai; József Jekó 📂 Article 📅 2006 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 411 KB 👁 1 views

The reaction of dibenzylideneacetones or E,E-cinnamylidene-acetophenones and hydrazine hydrate provided 1-propionyl derivatives of 5-aryl-3-styryl-2-pyrazolines and 3-aryl-5-styryl-2-pyrazolines. These unsaturated ketones afforded 1-(2-carboxyphenyl) or 1-(4-carboxyphenyl) 5-aryl-3-styryl-2-pyrazoli

Oxazepines and thiazepines. 41 . Synthes
✍ Albert Lévai 📂 Article 📅 2004 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 157 KB

## Abstract New 4‐aryl‐2,3‐dihydro‐2‐styryl‐1,5‐benzothiazepines **8–13** have been synthesized by an acid catalyzed reaction of 2‐arninothiophenol (**1**) and (__E,E__)‐cinnamylideneacetophenones **2–7.** Ring contraction of 1,5‐benzothiazepines **8–13** provided 2,2‐disubstituted 3‐acetyl‐2,3‐dih