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Synthesis of 2,6,10,14-Pentadecanetetrone, a δ-Tetraketone (“Harries' Tetraketone”)

✍ Scribed by Prof. Dr. Burchard Franck; Dr. Volker Scharf; Dipl.-Chem. Marieluise Schrameyer

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
231 KB
Volume
13
Category
Article
ISSN
0044-8249

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A new quinodimethane, 1,6-methano[10]annulene-3,4-quinodimethane (1), was generated and trapped by the Diels-Alder reactions with various dienophiles to provide 1,6-methano[10]annelenes 3 fused with a six-membered ring at the 3,4-positions, one of which was derived to a benzene ring analogue 4.