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Synthesis of 2,3,4-trisubstituted pyrroles via a facile reaction of vinyl azides and tosylmethyl isocyanide

✍ Scribed by Chen, Wenteng; Shao, Jiaan; Li, Zhi; Giulianotti, Marc A.; Yu, Yongping


Book ID
120312825
Publisher
NRC Research Press
Year
2012
Tongue
French
Weight
115 KB
Volume
90
Category
Article
ISSN
0008-4042

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One-Step Synthesis of Dialkyl 2-[(4-Meth
✍ Abdolali Alizadeh; Hassan Masrouri; Sadegh Rostamnia; Farnaz Movahedi 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 61 KB

## Abstract The reactive 1 : 1 adducts in the reaction between Ph~3~P and dialkyl acetylenedicarboxylates have been trapped with ‘tosylmethyl isocyanide’ (TsMIC; **1**) to yield dialkyl 2‐[(4‐methylphenyl)sulfonyl]‐1__H__‐pyrrole‐3,4‐dicarboxylates **3** (__Scheme 1__). The structures of the highly