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Synthesis of 2,3-Dihydroindoles, Indoles, and Anilines by Transition Metal-Free Amination of Aryl Chlorides

✍ Scribed by Beller, Matthias; Breindl, Claudia; Riermeier, Thomas H.; Tillack, Annegret


Book ID
115501982
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
126 KB
Volume
66
Category
Article
ISSN
0022-3263

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Intramolecular amination catalysed by ru
✍ S. Cenini; E. Bettettini; M. Fedele; S. Tollari πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 402 KB

The carbonylation in toluene of 2nitrochalcones at 20 bar and lOO"C, with Pd(TMB), as catalyst and TMPhen as cocatalyst (TMBH = 2,4,6-trimethyl benzoic acid; TMPhen = 3,4,7,8-tetramethyl-l,lO-phenantbroline) gave the corresponding 2-acyl indoles in 60-98% yields. The use as catalyst of Ru,(CO),, ac