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Synthesis of 2-dimethylaminomethylene-3-(dicyanomethylene)quinuclidine

✍ Scribed by L. I. Koikov; V. G. Granik; E. A. Lisitsa

Book ID
112713305
Publisher
Springer
Year
1994
Tongue
English
Weight
112 KB
Volume
28
Category
Article
ISSN
0091-150X

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Lithiation of 3-methoxymethyl quinuclidine N-oxide occurs regioselectively to generate the 2-lithio 3-methoxymethyl derivative which can be trapped out with non-enolisable electrophiles to give 2,3disubstituted quinuclidine N-oxide derivatives in good yield.