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Synthesis of 2-Cyclopentenones by Gold(I)-Catalyzed Rautenstrauch Rearrangement

✍ Scribed by Shi, Xiaodong; Gorin, David J.; Toste, F. Dean

Book ID
125528043
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
65 KB
Volume
127
Category
Article
ISSN
0002-7863

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## Multi-membered O,S-heterocycles R 0691 Rearrangement of Alkynyl Sulfoxides Catalyzed by Gold(I) Complexes. -Under gold(I) catalysis, differently substituted homopropargylic arylsulfoxides undergo a rearrangement to give benzothiepinones or benzothiopyrans, depending on the substitution pattern