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Synthesis of 2-chloro-3-oxoesters by reaction of the dianion of ethyl 2-chloroacetoacetate with electrophiles

✍ Scribed by Specowius, Verena; Rahn, Thomas; Adeel, Muhammad; Reim, Stefanie; Feist, Holger; Saghyan, Ashot S.; Langer, Peter

Book ID
119947777
Publisher
Springer Vienna
Year
2013
Tongue
English
Weight
316 KB
Volume
144
Category
Article
ISSN
0026-9247

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ChemInform Abstract: The Reaction of Ethyl 2-Chloroacetoacetate with 2-(Alkylamino) Alcohols: An Unexpected Formation of the 2-Methyloxazolidine Ring.
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The Reaction of Ethyl 2-Chloroacetoacetate with 2-(Alkylamino) Alcohols: An Unexpected Formation of the 2-Methyloxazolidine Ring. -The title reaction leads to unexpected oxazolidines, e.g. (III), rather than to the expected aza analogues of carboxin. -(NECHEV, L.;