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Synthesis of 2-arylacrylic esters from aryl methyl ketones via Wittig reaction/singlet oxygen ene reaction

✍ Scribed by Sangjoon Park; Dongsik Yang; Kyoung Tae Kim; Heung Bae Jeon

Book ID
113930077
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
899 KB
Volume
52
Category
Article
ISSN
0040-4039

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2-Aryl-3H-indol-3-ones (Sa-0) have been synthesized via methanol trapping reaction in singlet oxygenation of 2-arylindoles (la-o), followed by thermal decomposition of the resultant 2-. aryl-2-methoxy-3-oxc2,3-dihydroindoles (2a-0) in good yields.