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Synthesis of 2-Aminoazulene Derivatives. Nucleophilic and Palladium-Catalyzed Amination of 2-Substituted Azulene.

✍ Scribed by Ryuji Yokoyama; Shunji Ito; Tetsuo Okujima; Takahiro Kubo; Masafumi Yasunami; Akio Tajiri; Noboru Morita


Publisher
John Wiley and Sons
Year
2004
Weight
137 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract Selectively substituted phenanthridine derivatives are obtained by a facile reaction of __o__‐alkylated aryl iodides, __o__‐bromoarenesulfonylanilines and activated olefins in the presence of palladium and norbornene as catalysts. The reaction takes place under mild conditions to give t