Synthesis of 2-amino-2-deoxy-α-d-glucopyranosyl β-d-fructofuranoside (2-amino-2-deoxysucrose) via Koenigs-Knorr reaction
✍ Scribed by Shinkiti Koto; Shigeru Inada; Hiroki Ogawa; Shonosuke Zen
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 375 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0008-6215
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Condensation of benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-a-D-galactopyranoside with 2,3,4-tri-o-acetyl-a-D-fucopyranosyl bromide in 1: 1 nitromethane-benzene, in the presence of powdered mercuric cyanide, afforded benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-0-(2,3,4-tri-O-acetyl-P-D-fucopyran
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